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1 Department of Geoscience, University of Fribourg, Perolles, 1700 Fribourg,
Switzerland
2 EMPA, Swiss Federal Laboratories for Material Testing and Research, Hydrogen
and Energy, Ueberlandstrasse 129, Duebendorf 8600, Switzerland
3 Department of Mineralogy, Faculty of Geology, St. Petersburg State University,
Universitetskaya nab. 7/9, St. Petersburg 199034, Russia
4 Department of Crystallography, Faculty of Geology, St. Petersburg State
University, Universitetskaya nab. 7/9, St. Petersburg 199034, Russia
5 Institut für Geowissenschaften, Mineralogie-Geochemie, Universität
Freiburg, Albertstrasse 23b, 79104 Freiburg, Germany
* E-mail: daniel.wiedenmann{at}gmail.com
Alumoåkermanite,
(CaNa)2(Al,Mg,Fe2+)(Si2O7), is a
new mineral member of the melilite group from the active
carbonatite-nephelinite-phonolite volcano Oldoinyo Lengai, Tanzania. The
mineral occurs as tabular phenocrysts and microphenocrysts in
melilite-nephelinitic ashes and lapilli-tuffs. Alumoåkermanite is light
brown in colour; it is transparent, with a vitreous lustre and the streak is
white. Cleavages or partings are not observed. The mineral is brittle with an
uneven fracture. The measured density is 2.96(2) g/cm3. The Mohs
hardness is
4.5-6. Alumoåkermanite is uniaxial (-) with
=
1.635(1) and
= 1.624-1.626(1). In a 30 µm thin section (+N), the
mineral has a yellow to orange interference colour, straight extinction and
positive elongation, and is nonpleochroic. The average chemical formula of the
mineral derived from electron microprobe analyses is:
(Ca1.48Na0.50Sr0.02K0.01)
2.01(Al0.44Mg0.30
Mn0.01)
0.99(Si1.99Al0.01O7).
Alumoåkermanite is tetragonal, space group
P
21m with
a = 7.7661(4) Å, c = 5.0297(4) Å, V =
303.4(1) Å3 and Z = 2. The five strongest
powder-diffraction lines [d in Å,
(I/Io), hkl] are: 3.712, (13), (111);
3.075, (25), (201); 2.859, (100), (211); 2.456, (32), (311); 1.757, (19),
(312). Single-crystal structure refinement (R1 = 0.018)
revealed structure topology typical of the melilite-group minerals, i.e.
tetrahedral [(Al,Mg)(Si2O7)] sheets interleaved with
layers of (CaNa) cations. The name reflects the chemical composition of the
mineral.
KEYWORDS: alumoåkermanite, åkermanite, melilite, new mineral, volcanic rock, chemical composition, crystal structure, Oldoinyo Lengai, Tanzania
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